The Circuitous Journey from Malonamides to BTPhens: Ligands for Separating Actinides from Lanthanides

Hudson, Michael, Lewis, Frank and Harwood, Laurence (2014) The Circuitous Journey from Malonamides to BTPhens: Ligands for Separating Actinides from Lanthanides. In: Strategies and Tactics in Organic Synthesis. Elsevier, London, pp. 177-202. ISBN 978-0-08-099362-1

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Official URL: http://dx.doi.org/10.1016/B978-0-08-099362-1.00006...

Abstract

This account describes the scientific events that have led from malonamides, which co-extract minor actinides and fission products, to the 1,2,4 triazines such as BTBP and BTPhen reagents that are capable of separating Am(III) from Eu(III). The journey started with a walk in hot and dusty Rome with Claude Musikas of the CEA in 1980 and continues to a celebratory beer or two in Reading (2012) with Laurence Harwood and Frank Lewis. Throughout the journey, organic synthesis, coupled with coordination chemistry has been the engine by which successful science has developed.

Item Type: Book Section
Subjects: F100 Chemistry
F200 Materials Science
H800 Chemical, Process and Energy Engineering
Department: Faculties > Health and Life Sciences > Applied Sciences
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Depositing User: Frank Lewis
Date Deposited: 13 Jan 2014 14:02
Last Modified: 24 Oct 2017 11:24
URI: http://nrl.northumbria.ac.uk/id/eprint/15056

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