Stability and reactivity of the α-cyclodextrin complexes of 4-methylperbenzoic acid

Davies, Martin and Deary, Michael (1996) Stability and reactivity of the α-cyclodextrin complexes of 4-methylperbenzoic acid. Journal of Physical Organic Chemistry, 9 (6). pp. 433-435. ISSN 0894 3230

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Official URL: http://dx.doi.org/10.1002/(SICI)1099-1395(199606)9...

Abstract

A kinetic study of the α-cyclodextrin-mediated oxidation of methyl 4-nitrophenyl sulphide by 4-methylperbenzoic acid suggests that the stability constant for the cyclodextrin-peracid complex is two orders of magnitude greater than the value determined previously. Potentiometric studies confirmed this and showed that the 4-methylperbenzoate anion forms a complex of stability similar to that of the molecular acid. A less stable 2 : 1 cyclodextrin-4-methylperbenzoic acid complex is also observed.

Item Type: Article
Subjects: F100 Chemistry
Department: Faculties > Engineering and Environment > Geography
Depositing User: Becky Skoyles
Date Deposited: 18 Feb 2015 11:08
Last Modified: 10 Aug 2015 11:35
URI: http://nrl.northumbria.ac.uk/id/eprint/18601

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