An unusual ready inversion of sp3 skeletal carbon in an organometallic complex

Bookham, Jonathan (1998) An unusual ready inversion of sp3 skeletal carbon in an organometallic complex. Inorganic Chemistry Communications, 1 (8). pp. 309-313. ISSN 1387-7003

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Abstract

Quantitative inversion at the chiral sp3 hybridised carbon atoms in the octahedral tetracarbonyl tungsten(0) chelate complex of the C2 chiral diphosphine Ph2PCHArCHArPPh2 (Ar=2-pyridyl) occurs at moderately elevated temperatures.

Item Type: Article
Uncontrolled Keywords: Carbonyl complexes; Diphosphine complexes; Inversion; Tungsten complexes
Subjects: F100 Chemistry
Department: Faculties > Health and Life Sciences > School of Life Sciences > Applied Sciences
Depositing User: Becky Skoyles
Date Deposited: 05 Feb 2015 14:53
Last Modified: 10 Aug 2015 11:52
URI: http://nrl.northumbria.ac.uk/id/eprint/19504

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