Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy

Bookham, Jonathan and McFarlane, William (1993) Chiral ligands: Unambiguous assignment of absolute configuration by NMR spectroscopy. Journal of the Chemical Society, Chemical Communications (17). pp. 1352-1354. ISSN 0022 4936

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Official URL: http://dx.doi.org/10.1039/C39930001352

Abstract

Two-dimensional rotating-frame nuclear Overhauser enhancement (ROESY) spectra are used to determine the relative configurations at the chiral carbon atoms in the two diastereoisomers of [o-C6H4CHMeNMe 2Pd(Ph2PCHMeCHMePPh2)]+PF 6- derived from (+) Ph2PCHMeCHMePPh2 1 and [o-C6H4CHMeNMe2PdCl]2 of known configurations, and hence to show that the (+) form of 1 has the R,Rconfiguration.

Item Type: Article
Subjects: F100 Chemistry
Department: Faculties > Health and Life Sciences > Applied Sciences
Depositing User: Becky Skoyles
Date Deposited: 28 Jan 2015 13:18
Last Modified: 24 Oct 2017 11:28
URI: http://nrl.northumbria.ac.uk/id/eprint/20216

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