Kozhevnikov, Valery, Ustinova, Maria M., Slepukhin, Pavel A., Santoro, A., Bruce, D. W. and Kozhevnikov, Dmitry N. (2008) From 1,2,4-triazines towards substituted pyridines and their cyclometallated Pt complexes. Tetrahedron Letters, 49 (26). pp. 4096-4098. ISSN 0040-4039Full text not available from this repository.
A new, efficient methodology for the synthesis of substituted thienylpyridines includes the synthesis of 3-thienyl-1,2,4-triazines using simple heterocyclisation followed by easy transformation of the triazine ring to a pyridine through an aza Diels–Alder approach. A variety of substituted pyridines can be easily achieved using cheap, commercially available reagents such as bromoacetylarenes, aroyl hydrazides, norbornadiene, and enamines in various combinations. New thienylpyridines form phosphorescent cyclometallated Pt complexes.
|Divisions:||Faculties > Health and Life Sciences > School of Life Sciences > Chemical and Forensic Sciences|
|Depositing User:||EPrints Services|
|Date Deposited:||25 Feb 2010 12:17|
|Last Modified:||22 Feb 2013 10:05|
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