Advances in designs and mechanisms of semiconducting metal oxide nanostructures for high-precision gas sensors operated at room-temperature

Li, Zhijie, Li, Hao, Wu, Zhonglin, Wang, Mingkui, Luo, Jingting, Torun, Hamdi, Hu, Pingan, Yang, Chang, Grundmann, Marius, Liu, Xiaoteng and Fu, Yong Qing (2019) Advances in designs and mechanisms of semiconducting metal oxide nanostructures for high-precision gas sensors operated at room-temperature. Materials Horizon, 6 (3). pp. 470-506. ISSN 2051-6347

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Official URL: http://doi.org/10.1039/C8MH01365A

Abstract

High-precision gas sensors operated at room temperature are attractive for various real-time gas monitoring applications, with advantages including low energy consumption, cost effectiveness and device miniaturization/flexibility. Sensing materials, which play a key role for the good gas sensing performance, are currently focused extensively on semiconducting metal oxide nanostructures (SMONs) used in the conventional resistance type gas sensors. This topical review highlights the designs and mechanisms of different SMONs with various patterns (e.g. nanoparticles, nanowires, nanosheets, nanorods, nanotubes, nanofilms, etc.) for gas sensors to detect various hazardous gases at the room temperature. The key topics include: (1) single phase SMONs including both n-type and p-type ones; (2) noble metal nanoparticles and metal ion modified SMONs; (3) composite oxides of SMONs; (4) composites of SMONs with carbon nanomaterials. Enhancement of sensing performance of the SMONs at the room temperature can also be enhanced using photo-activation effect such as ultraviolet light. The SMON based mechanically flexible and wearable room temperature gas sensors are also discussed. Various mechanisms have been discussed for the enhanced sensing performance, which include redox reactions, heterojunction generation, formation of metal sulfides and spillover effect. Finally, major challenges and prospects for the SMONs based room temperature gas sensors are highlighted.

Item Type: Article
Uncontrolled Keywords: Semiconducting metal oxide; Nanostructure; Gas sensor; Hazardous gas; Sensing mechanism; Sensing performance
Subjects: F200 Materials Science
Department: Faculties > Engineering and Environment > Mathematics, Physics and Electrical Engineering
Depositing User: Becky Skoyles
Date Deposited: 11 Dec 2018 14:59
Last Modified: 18 Apr 2019 08:31
URI: http://nrl.northumbria.ac.uk/id/eprint/37190

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