Continuous methane measurements from a late Holocene Greenland ice core: Atmospheric and in-situ signals

Rhodes, Rachael H., Faïn, Xavier, Stowasser, Christopher, Blunier, Thomas, Chappellaz, Jérôme, McConnell, Joseph R., Romanini, Daniele, Mitchell, Logan E. and Brook, Edward J. (2013) Continuous methane measurements from a late Holocene Greenland ice core: Atmospheric and in-situ signals. Earth and Planetary Science Letters, 368. pp. 9-19. ISSN 0012-821X

Full text not available from this repository. (Request a copy)
Official URL:


Ancient air trapped inside bubbles in ice cores can now be analysed for methane concentration utilising a laser spectrometer coupled to a continuous melter system. We present a new ultra-high resolution record of atmospheric methane variability over the last 1800 yr obtained from continuous analysis of a shallow ice core from the North Greenland Eemian project (NEEM-2011-S1) during a 4-week laboratory-based measurement campaign. Our record faithfully replicates the form and amplitudes of multi-decadal oscillations previously observed in other ice cores and demonstrates the detailed depth resolution (5.3 cm), rapid acquisition time (30 m day−1) and good long-term reproducibility (2.6%, 2σ) of the continuous measurement technique.

In addition, we report the detection of high frequency ice core methane signals of non-atmospheric origin. Firstly, measurements of air from the firn–ice transition region and an interval of ice core dating from 1546–1560 AD (gas age) resolve apparently quasi-annual scale methane oscillations. Traditional gas chromatography measurements on discrete ice samples confirm these signals and indicate peak-to-peak amplitudes of ca. 22 parts per billion (ppb). We hypothesise that these oscillations result from staggered bubble close-off between seasonal layers of contrasting density during time periods of sustained multi-year atmospheric methane change. Secondly, we report the detection of abrupt (20–100 cm depth interval), high amplitude (35–80 ppb excess) methane spikes in the NEEM ice that are reproduced by discrete measurements. We show for the first time that methane spikes present in thin and infrequent layers in polar, glacial ice are accompanied by elevated concentrations of carbon- and nitrogen-based chemical impurities, and suggest that biological in-situ production may be responsible.

Item Type: Article
Department: Faculties > Engineering and Environment > Geography and Environmental Sciences
Depositing User: Elena Carlaw
Date Deposited: 17 Jan 2019 13:55
Last Modified: 17 Jan 2019 13:55

Actions (login required)

View Item View Item


Downloads per month over past year

View more statistics

Policies: NRL Policies | NRL University Deposit Policy | NRL Deposit Licence