Conformationally Driven Two- and Three-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles

Koovits, Paul J., Knowles, Jonathan P. and Booker-Milburn, Kevin I. (2016) Conformationally Driven Two- and Three-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles. Organic Letters, 18 (21). pp. 5608-5611. ISSN 1523-7060

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Official URL: https://doi.org/10.1021/acs.orglett.6b02829

Abstract

A TBSO group has been shown to exert a high degree of stereocontrol during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover, this and other bulky groups have been shown to change the outcome of the reaction, promoting a new two-photon sequence to tricyclic imines and an unprecedented stereoselective three-photon sequence to azabicyclo[3.3.1]nonanes.

Item Type: Article
Subjects: F100 Chemistry
H800 Chemical, Process and Energy Engineering
Department: Faculties > Health and Life Sciences > Applied Sciences
Depositing User: Elena Carlaw
Date Deposited: 15 Mar 2019 15:06
Last Modified: 15 Mar 2019 15:15
URI: http://nrl.northumbria.ac.uk/id/eprint/38421

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