Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

Kozhevnikov, Valery, Dahms, Katja and Bryce, Martin (2011) Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes. The Journal of Organic Chemistry, 76 (12). pp. 5143-5148. ISSN 0022-3263

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Official URL: http://dx.doi.org/10.1021/jo200357e

Abstract

New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.

Item Type: Article
Subjects: C700 Molecular Biology, Biophysics and Biochemistry
F100 Chemistry
F400 Forensic and Archaeological Science
Department: Faculties > Health and Life Sciences > School of Life Sciences > Applied Sciences
Depositing User: Ellen Cole
Date Deposited: 19 Dec 2011 16:12
Last Modified: 10 Aug 2015 11:40
URI: http://nrl.northumbria.ac.uk/id/eprint/4307

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