Santoro, A., Prokhorov, Anton, Kozhevnikov, Valery, Whitwood, Adrian C., Donnio, Bertrand, Williams, J. A. G. and Bruce, D. W. (2011) Emissive Metallomesogens Based on 2-Phenylpyridine Complexes of Iridium(III). Journal of the American Chemical Society, 133 (14). pp. 5248-5251. ISSN 0002-7863Full text not available from this repository.
Preparation of IrIII complexes using anisotropic 2,5-di(4-alkoxyphenyl)pyridine ligands leads to emissive, liquid-crystalline complexes containing bound Cl and dimethyl sulfoxide. Using analogous poly(alkoxy) ligands allows the preparation of bis(2-phenylpyridine)iridium(III) acac complexes, which are also mesomorphic. The observation of liquid crystallinity in octahedral complexes of this type is without precedent.
|Uncontrolled Keywords:||liquid crystals, cyclometallated iridium complexes, luminescence|
|Divisions:||Faculties > Health and Life Sciences > School of Life Sciences > Biomolecular and Biomedical Research Centre|
Faculties > Health and Life Sciences > School of Life Sciences > Chemical and Forensic Sciences
|Depositing User:||Ay Okpokam|
|Date Deposited:||14 Feb 2012 16:33|
|Last Modified:||22 Feb 2013 10:12|
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