Persistent Dimer Emission in Thermally Activated Delayed Fluorescence Materials

Etherington, Marc, Kukhta, Nadzeya A., Higginbotham, Heather F., Danos, Andrew, Bismillah, Aisha N., Graves, David R., McGonigal, Paul R., Haase, Nils, Morherr, Antonia, Batsanov, Andrei S., Pflumm, Christof, Bhalla, Vandana, Bryce, Martin R. and Monkman, Andrew P. (2019) Persistent Dimer Emission in Thermally Activated Delayed Fluorescence Materials. The Journal of Physical Chemistry C, 123 (17). pp. 11109-11117. ISSN 1932-7447

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Official URL: http://dx.doi.org/10.1021/acs.jpcc.9b01458

Abstract

We expose significant changes in the emission color of carbazole-based thermally activated delayed fluorescence (TADF) emitters that arise from the presence of persistent dimer states in thin films and organic light-emitting diodes (OLEDs). Direct photoexcitation of this dimer state in 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) reveals the significant influence of dimer species on the color purity of its photoluminescence and electroluminescence. The dimer species is sensitive to the sample preparation method, and its enduring presence contributes to the widely reported concentration-mediated red shift in the photoluminescence and electroluminescence of evaporated thin films. This discovery has implications on the usability of these, and similar, molecules for OLEDs and explains disparate electroluminescence spectra presented in the literature for these compounds. The dimerization-controlled changes observed in the TADF process and photoluminescence efficiency mean that careful consideration of dimer states is imperative in the design of future TADF emitters and the interpretation of previously reported studies of carbazole-based TADF materials.

Item Type: Article
Subjects: F100 Chemistry
F200 Materials Science
Department: Faculties > Engineering and Environment > Mathematics, Physics and Electrical Engineering
Depositing User: Ay Okpokam
Date Deposited: 08 Jan 2020 17:04
Last Modified: 03 Jul 2020 08:00
URI: http://nrl.northumbria.ac.uk/id/eprint/41858

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