Tuning the synthesis of polymetallic-doped ZIFs derived materials for efficient hydrogenation of furfural to furfuryl alcohol

Fan, Yafei, Li, Shangjing, Wang, Ying, Zhuang, Changfu, Liu, Xiaoteng, Guangshan, Zhu and Zou, Xiaoqin (2020) Tuning the synthesis of polymetallic-doped ZIFs derived materials for efficient hydrogenation of furfural to furfuryl alcohol. Nanoscale. ISSN 2040-3364 (In Press)

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Official URL: https://doi.org/10.1039/D0NR04098C

Abstract

Cu, Co and Zn modified N-doped porous carbons (CuCo/Zn@NPC) are prepared using a polymetallic homogeneous doping and self-templating method as high performance non-noble metal catalysts for the hydrogenation of furfural (FF) to furfuryl alcohol (FAL). The CuCo/Zn@NPC-600 catalyst after treated at 600 oC shows a superior catalytic activity with nearly 100% conversion of FF and an almost 100% selectivity of FAL using H2 at 140 oC. Meanwhile in the catalytic transfer hydrogenation (CTH) using 2-propanol as H-donor, the conversion of FF reaches 95.8% and the selectivity of FAL is 99.1%. The results show that the Zn dopant leads to 37.3 times higher yield on CuCo/Zn@NPC-600 catalyst than that on CuCo@NPC-600, and 2.3 times higher than that of Co/Zn@NPC-600 with Cu dopant. The efficient activity of the CuCo/Zn@NPC-600 catalyst is mainly due to the highly dispersed metal nanoparticles, the advanced porous structure resulted from Zn escape from the precursor template, and the synergistic effect between Cu and Co. Furthermore, the CuCo/Zn@NPC-600 catalyst exhibits good recyclability of FF hydrogenation in four cycle tests. The advanced synthesis of using homogeneous doping and self-template strategy sheds light on preparing effective catalysts for hydrogenation of biomass-based compounds.

Item Type: Article
Subjects: D500 Forestry
D700 Agricultural Sciences
F200 Materials Science
Department: Faculties > Engineering and Environment > Mechanical and Construction Engineering
Depositing User: John Coen
Date Deposited: 06 Aug 2020 09:51
Last Modified: 06 Aug 2020 10:00
URI: http://nrl.northumbria.ac.uk/id/eprint/44011

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