Crystalline and porous CoSe dendrimeric architectures for efficient oxygen evolution reaction

Bilal, Muhammad, Rashid, , Altaf, Amna, Baig, Nadeem, Chotana, Ghayoor Abbas, Ashraf, Raja Shahid, Rasul, Shahid, Nafady, Ayman, Ul-Hamid, Anwar and Sohail, Manzar (2022) Crystalline and porous CoSe dendrimeric architectures for efficient oxygen evolution reaction. Fuel, 323. p. 124324. ISSN 0016-2361

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Official URL: https://doi.org/10.1016/j.fuel.2022.124324

Abstract

Developing an efficient and economical electrocatalyst for oxygen evolution reaction is the key challenge to renewable energy technologies. Metal selenides are attractive candidates for electrocatalytic water oxidation because they provide suitable surface-active sites for the reaction. Herein, we report less explored hexagonal cobalt selenide (CoSe) preparation for oxygen evolution reaction through the facile and environmentally benign one-step hydrothermal method. Reaction conditions were precisely tailored to develop highly crystalline and porous dendrimeric architectures of CoSe. Owing to its exclusive porous and dendrimeric crystalline network and large electrochemical surface area, the superior CoSe electrocatalyst (that is 16H) showed excellent electrochemical activity with remarkably low overpotential (250 mV at 10 mA cm−2) and very high current density (570 mA cm−2) in a small potential window. The Tafel slope of 16H sample was 56 mV dec−1, indicating the faster kinetics at the catalyst surfaces. Moreover, it also showed excellent stability under harsh oxidative conditions in a 24-hour long stability test experiment.

Item Type: Article
Additional Information: Funding Information: The Higher Education Commission (HEC) , Pakistan, supported this work through grant No. HEC-HEDP LCF 07 & We extend our sincere appreciation to Researchers Supporting Program (RSP-2022/79) at King Saud University , Riyadh, Saudi Arabia.
Uncontrolled Keywords: CoSe, Electrocatalyst, Oxygen evolution reaction, Renewable energy, Water splitting
Subjects: F100 Chemistry
H800 Chemical, Process and Energy Engineering
Department: Faculties > Engineering and Environment > Mechanical and Construction Engineering
Depositing User: Rachel Branson
Date Deposited: 01 Jun 2022 08:59
Last Modified: 01 Jun 2022 09:00
URI: http://nrl.northumbria.ac.uk/id/eprint/49241

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