Probert, Michael, Ramsden, Christopher and Stanforth, Stephen (2017) Addition of phenylisocyanate to 3,5-diphenyl-1,2-dithiolium-4-olate gives a thioketone. Tetrahedron Letters, 58 (14). pp. 1425-1427. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2017.02.076
Abstract
The Type B mesoionic heterocycle, 3,5-diphenyl-1,2-dithiolium-4-olate, reacts with phenylisocyanate producing a thioketone derivative rather than a pseudo-semi-conjugated heterocyclic mesomeric betaine. The structure of the thioketone product was confirmed by an X-ray crystallographic investigation.
| Item Type: | Article |
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| Uncontrolled Keywords: | mesomeric betaine, mesoionic, semi-conjugated |
| Subjects: | F100 Chemistry |
| Department: | Faculties > Health and Life Sciences > Applied Sciences |
| Depositing User: | Becky Skoyles |
| Date Deposited: | 27 Feb 2017 10:17 |
| Last Modified: | 17 Dec 2023 16:45 |
| URI: | https://nrl.northumbria.ac.uk/id/eprint/29872 |
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