Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology

Stanforth, Stephen, Tarbit, Brian and Watson, Michael (2003) Synthesis of 2,2′-bipyridyl derivatives using aza Diels-Alder methodology. Tetrahedron Letters, 44 (4). pp. 693-694. ISSN 0040 4039

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Official URL: http://dx.doi.org/10.1016/S0040-4039(02)02670-9

Abstract

Amidrazone 1 and the tricarbonyl derivatives 2a-c gave the triazines 3a-c, respectively, which reacted with 2,5-norbornadiene 4 in boiling ethanol yielding the corresponding novel 2,2′-bipyridines 5a-c in good yield. Triazine 6 gave the 2,2′-bipyridyl derivative 7 (65%) with compound 4 in 1,2-dichlorobenzene at 140°C. © 2003 Elsevier Science Ltd. All rights reserved.

Item Type: Article
Uncontrolled Keywords: 1,2,4-triazines, 2,2′-bipyridyls, Aza Diels-Alder reaction
Subjects: F100 Chemistry
Department: Faculties > Health and Life Sciences > Applied Sciences
Depositing User: Becky Skoyles
Date Deposited: 12 Feb 2015 11:02
Last Modified: 12 Oct 2019 17:29
URI: http://nrl.northumbria.ac.uk/id/eprint/19463

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