Suitability of Atmospheric-pressure MOCVD CdTe Solar Cells for Inline Production Scale

Barrioz, Vincent, Lamb, Daniel, Jones, Eurig and Irvine, Stuart (2009) Suitability of Atmospheric-pressure MOCVD CdTe Solar Cells for Inline Production Scale. MRS Proceedings, 1165. ISSN 1946-4274

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Abstract

CdTe, with a direct band gap of 1.45 eV is well suited to the terrestrial AM1.5 solar irradiance and currently makes up half of the thin film (TF) photovoltaic (PV) market. There are 4 main factors that determine final cost of PV modules: the conversion efficiency, materials amount per unit area of module, production yield, and the economy of scale. It is therefore valuable to investigate alternative and/or innovative deposition techniques and processes which have the potential to impact on these factors. Metal organic chemical vapour deposition (MOCVD) is a powerful technique offering increased process repeatability, achieving a high level of control of materials characteristics. Recent improvements in CdTe devices using atmospheric–pressure (AP) MOCVD have led to efficiencies of 13.3 % using 2 μm absorber layers and 11 % with a 1 μm absorber layer [11, 12]. These results were achieved: by extending the optical band gap of the window layer, using a ternary alloy (Cd0.9Zn0.1S), with intentional p-type doping of the CdTe layers with As, and the use of an in situ (dry) deposited CdCl2 layer and anneal. All layers, except the front and back contact, are grown by a sequential MOCVD process. Furthermore this is a dry process without the need for any etch treatment. The inherent design of the horizontal MOCVD laboratory chambers do not lend themselves well to large scale production. However, the CSER group has designed and built an experimental inline reaction chamber to evaluate AP-MOCVD as an inline production process. Discussion is made based on kinetically limited growth and molar supply models to assess the suitability of the MOCVD process to deposit fast enough for an inline process. The AP-MOCVD inline reactor uses a showerhead to deliver the precursors onto a moving 5 × 7.5 cm2 substrate and preliminary results for deposited layers are given. From these preliminary results it has been extrapolated that a 1 μm thick CdTe layer can be deposited on substrates moving at 60 cm/min.

Item Type:	Article
Uncontrolled Keywords:	II-VI; kinetics; photovoltaic
Subjects:	F200 Materials Science
Department:	Faculties > Engineering and Environment > Mathematics, Physics and Electrical Engineering
Depositing User:	Becky Skoyles
Date Deposited:	23 Nov 2015 16:26
Last Modified:	12 Oct 2019 19:06
URI:	http://nrl.northumbria.ac.uk/id/eprint/24707

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