Connelly, Rickki L., Knowles, Jonathan P. and Booker-Milburn, Kevin I. (2019) A Rapid Synthetic Approach to the ABCD Core of the Stemona Alkaloids. Organic Letters, 21 (1). pp. 18-21. ISSN 1523-7060
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Connelly et al - A Rapid Stereoselective Approach to ABCD core of the Stemona Alkaloids AAM.pdf - Accepted Version Download (727kB) | Preview |
Official URL: http://dx.doi.org/10.1021/acs.orglett.8b03371
Abstract
A new Lewis acid-assisted Brønsted acid cascade approach for the stereoselective formation of the tetracyclic Stemona alkaloid skeleton is described in five steps from epoxide 15. Crucially, this tetracyclic product can be accessed as either C13 epimer, potentially serving as intermediates for the synthesis of a range of Stemona alkaloids.
| Item Type: | Article |
|---|---|
| Subjects: | F100 Chemistry |
| Department: | Faculties > Health and Life Sciences > Applied Sciences |
| Depositing User: | Paul Burns |
| Date Deposited: | 22 Feb 2019 11:43 |
| Last Modified: | 31 Jul 2021 20:19 |
| URI: | http://nrl.northumbria.ac.uk/id/eprint/38200 |
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