Koovits, Paul J., Knowles, Jonathan P. and Booker-Milburn, Kevin I. (2016) Conformationally Driven Two- and Three-Photon Cascade Processes in the Stereoselective Photorearrangement of Pyrroles. Organic Letters, 18 (21). pp. 5608-5611. ISSN 1523-7060
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Official URL: https://doi.org/10.1021/acs.orglett.6b02829
Abstract
A TBSO group has been shown to exert a high degree of stereocontrol during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover, this and other bulky groups have been shown to change the outcome of the reaction, promoting a new two-photon sequence to tricyclic imines and an unprecedented stereoselective three-photon sequence to azabicyclo[3.3.1]nonanes.
| Item Type: | Article |
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| Subjects: | F100 Chemistry H800 Chemical, Process and Energy Engineering |
| Department: | Faculties > Health and Life Sciences > Applied Sciences |
| Depositing User: | Elena Carlaw |
| Date Deposited: | 15 Mar 2019 15:06 |
| Last Modified: | 01 Aug 2021 12:37 |
| URI: | http://nrl.northumbria.ac.uk/id/eprint/38421 |
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