Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3 −Ru Pincer Complex

Min, Shixiong, Rasul, Shahid, Li, Huaifeng, Grills, David C., Takanabe, Kazuhiro, Li, Lain-Jong and Huang, Kuo-Wei (2016) Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3 −Ru Pincer Complex. ChemPlusChem, 81 (2). pp. 166-171. ISSN 2192-6506

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Abstract

A well-defined PN3-Ru pincer complex (5) bearing a redox-active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO2 reduction to CO and HCOOH with negligible formation of H2 in a H2O/MeCN mixture. Done in a pince: A PN3-Ru pincer complex (see figure) has been found to show high activity and stability as a molecular electrocatalyst for CO2 reduction to CO and HCOOH in MeCN/H2O.

Item Type:	Article
Uncontrolled Keywords:	electrocatalysts, electrochemistry, N,P ligands, redox, ruthenium
Subjects:	F100 Chemistry
Department:	Faculties > Engineering and Environment > Mechanical and Construction Engineering
Depositing User:	Paul Burns
Date Deposited:	09 Apr 2019 09:01
Last Modified:	10 Oct 2019 20:18
URI:	http://nrl.northumbria.ac.uk/id/eprint/38848

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