Ultrastable PtCo/Co3O4–SiO2 Nanocomposite with Active Lattice Oxygen for Superior Catalytic Activity toward CO Oxidation

Wu, Dandan, Jia, Runping, Wen, Ming, Zhong, Shuai, Wu, Qingsheng, Fu, Richard and Yu, Shuhong (2020) Ultrastable PtCo/Co3O4–SiO2 Nanocomposite with Active Lattice Oxygen for Superior Catalytic Activity toward CO Oxidation. Inorganic Chemistry, 59 (2). pp. 1218-1226. ISSN 0020-1669

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Abstract

A nanostructural catalyst with long-term durability under harsh conditions is very important for an outstanding catalytic performance. Herein, a new ultrastable PtCo/Co3O4–SiO2 nanocatalyst was explored to improve the catalytic performance of carbon monoxide (CO) oxidation by virtue of the surface active lattice oxygen derived from strong metal–support interactions. Such a structure can overcome the issues of Co3O4–SiO2 inactivation by water vapor and the Pt inferior activity at low temperature. Further, Co3O4–SiO2 nanosheets endow superior structure stability under high temperatures of up to 800 °C, which gives long-term catalytic cyclability of PtCo/Co3O4–SiO2 nanocomposites for CO oxidation. Moreover, the large specific surface areas (294 m2 g–1) of the nanosheet structure can expose abundant surface active lattice oxygen, which significantly enhanced the catalytic activity of CO oxidation at 50 °C over 30 days without apparent aggregation of PtCo nanoparticles after 20 cycles from 50 to 400 °C. It can be expected to be a promising candidate as an ultrastable efficient catalyst.

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